Tuesday, August 24, 2021

Redox Reaction: Chemistry

  • Answers are in BOLD Option name.

 Q.1.  The oxidation state of nitrogen in N subscript 3 H  is 

A) plus 1 half

B) +3

C) -1

D) negative 1 third 

Explanation-

stack straight N subscript 3 with straight x on top straight H with plus 1 on top space straight i. straight e. comma space 3 space left parenthesis straight x right parenthesis space plus 1 left parenthesis plus 1 right parenthesis equals 0 space space rightwards double arrow space straight x equals negative 1 third 


Q.2. A,B and C are three elements forming a part of compound in oxidation states of +2,+5 and -2 respectively. What could be the compound if molecule is neutral ?

A) Ablank subscript 2(BC)blank subscript 2

B) Ablank subscript 2(BCblank subscript 4)blank subscript 3

C) Ablank subscript 3(BCblank subscript 4)blank subscript 2

D) ABC

Explanation-

straight A subscript 3 left parenthesis BC subscript 4 right parenthesis subscript 2 3 open parentheses plus 2 close parentheses plus 2 open square brackets 1 open parentheses plus 5 close parentheses plus 4 open parentheses negative 2 close parentheses close square brackets equals 6 plus 2 open parentheses negative 3 close parentheses equals 0

As the molecule is neutral , the sum of oxidation numbers must be zero .


Q.3. If three electrons are lost by a metal ion M to the power of 3 plus end exponent , its final oxidation number would be 

A) Zero

B) +6

C) +2

D) +3

Explanation-

straight M with 3 plus on top rightwards arrow straight M with 6 plus on top plus 3 straight e to the power of minus 


Q.4.  The oxidation number of chromium in K subscript 2 C r subscript 2 O subscript 7 is 

A) -6

B) +6

C) +2

D) -2

Explanation-

stack straight K subscript 2 with plus 1 on top stack Cr subscript 2 with straight x on top stack straight O subscript 7 with negative 2 on top space straight i. straight e. comma space 2 open parentheses plus 1 close parentheses plus 2 open parentheses straight x close parentheses plus 7 open parentheses negative 2 close parentheses equals 0 space space rightwards double arrow straight x equals plus 6 


Q.5.  The colour of K subscript 2 C r subscript 2 O subscript 7 changes from red orange to lemon yellow on treatment with aqueous KOH because of 

A) Reduction of Cr(VI) to (III)

B) Formation of chromium ion and chromate ion 

C) Conversion of dichromate ion to chromate ion 

D) Oxidation of potassium hydroxide to potassium peroxide 

Explanation-

IN basic medium , dichromate ion changes to chromate ion 

straight K subscript 2 Cr subscript 2 straight O subscript 7 plus 2 KOH rightwards harpoon over leftwards harpoon 2 straight K subscript 2 CrO subscript 4 plus straight H subscript 2 straight O 


Q.6.  Which pf the following species do not show disproportionation reaction ?

A) CIOblank to the power of minus

B) CIOblank to the power of minusblank subscript 2 

C) CIOblank to the power of minus subscript 3

D) CIOblank to the power of minus subscript 4 

Explanation-

CIO subscript 4 superscript minus  does not disproportionate because in this oxoanion chlorine is present in its highest oxidation state that is , + 7. The disproportionation reactions for  the other three oxoanions of chlorine are as follows :

3 straight C with plus 1 on top IO to the power of minus rightwards arrow 2 straight C with negative 1 on top straight I to the power of minus plus straight C with plus 5 on top IO subscript 3 superscript minus
3 straight C with plus 3 on top IO subscript 2 superscript minus rightwards arrow with hv on top 2 straight C with plus 5 on top IO subscript 3 superscript minus plus straight C with negative 1 on top straight I to the power of minus
4 straight C with plus 5 on top IO subscript 3 superscript minus rightwards arrow stack straight C to the power of minus with negative 1 on top plus 3 straight C with plus 7 on top IO subscript 4 superscript minus 


Q.7.  Which of the following is an example of displacement reaction ?

A) X+Yrightwards arrowZ

B) X+YZrightwards arrowXZ+Y

C) Zrightwards arrowX+Y

D) None of these 

Explanation-

The reaction in which an atom or ion in a compound is displaced by another atom or ion is known as displacement reaction .


Q.8. In Ostwald's process for the manufacture of nitric acid , the first step involves the oxidation of ammonia gas by oxygen gas to give nitric oxide gas and steam .What is the maximum weight of nitric oxide that can be obtained starting only with 10.00 g of ammonia and 20.00 g of oxygen ?

A) 10 g

B) 120 g

C) 15 g

D) 20 g

Explanation-

The reaction involved in the manufacturing process is : 

stack 4 NH subscript 3 left parenthesis straight g right parenthesis end subscript with stack 4 space mol with 4 cross times 17 equals 68 space straight g below below space plus stack 5 straight O subscript 2 with stack 5 space mol with 5 cross times 32 equals 160 space straight g below below space rightwards arrow space stack 4 NO subscript open parentheses straight g close parentheses end subscript with stack 4 space mol with 4 cross times 30 equals 120 space straight g below below space plus space 6 straight H subscript 2 straight O subscript open parentheses straight g close parentheses end subscript

68 of NHblank subscript 3 reacts with 160 g Oblank subscript 2 to produce 120 g of NOblank subscript open parentheses straight g close parentheses end subscript  . 

therefore  10 g of ammonia will require 23.52 g of Oblank subscript 2 react completely . 

but oxygen which is actually available is 20.0 g . Therefore ,

oxygen is the limiting reagent .

Now 160 g of Oblank subscript 2 will form NO = 120 g

therefore 20 g of Oblank subscript 2 will form NO = fraction numerator open parentheses 120 close parentheses over denominator open parentheses 160 close parentheses end fraction cross times open parentheses 20 close parentheses equals 15 space straight g 


Q.9.  In C r subscript 2 O subscript 7 to the power of 2 minus end exponent the oxidation numbers of Cr and O are 

A) O = + 2 , Cr = - 6

B) O = + 3 , Cr = +5

C) O = + 6 , Cr = - 6

D) O = - 2 , Cr = + 6

Explanation-

Oxidation state of oxygen is - 2 and that Cr can be calculate as 

Cr subscript 2 straight O subscript 7 superscript 2 minus end superscript
2 straight x minus 14 equals negative 2
straight x equals plus 6 


Q.10.  The number of electrons involved in the reduction of one nitrate ion to hydrazine is 

A) 0

B) 2

C) 6

D) 5

Explanation-

Oxidation state of N in NO subscript 3 superscript minus - is + 5 .Oxidation state of N in straight N subscript 2 straight H subscript 4 is - 2 .

So number of electrons involved in the reduction of one nitrate ion to hydrogen is 6 .

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