Thursday, August 19, 2021

P Block Elements: Chemistry Entrance

 


Q.1. Which of the following is a tetrabasic acid ?

A) Orthophosphoric acid

B) Hypo phosphorous acid

C) Metaphosphoric acid

D) Pyrophosphoric acid

Explanation-

Pyrophosphoric acid : straight H subscript 4 straight P subscript 2 straight O subscript 7

(Tetrabasic) table row blank straight O blank blank blank blank row blank cell vertical line vertical line end cell blank blank blank blank row HO minus straight P minus straight O minus row blank vertical line blank blank blank blank row blank OH blank blank blank blank end table table row straight O row cell table row cell vertical line vertical line end cell row straight P row vertical line end table end cell row OH end table table row cell table row blank row blank row minus end table end cell row blank row blank end table table row cell table row blank row blank row OH end table end cell row blank row blank end table 


Q.2. When ammonia is passed over heated copper oxide, the metallic copper is obtained, The reaction shows that ammonia is

A) A dehydrating agent

B) An oxidizing agent

C) A reducing agent

D) A nitrating agent

Explanation-

2 NH with negative 3 on top subscript 3 space plus space 3 stack CuO space with plus 2 on top rightwards arrow with triangle on top straight N with 0 on top subscript 2 space plus space 3 Cu with 0 on top space plus space 3 straight H subscript 2 straight O 


Q.3.  Which is the most amphoteric oxide ?

A) Nablank subscript 2O

B) MgO

C) Alblank subscript 2Oblank subscript 3

D) CaO

Explanation-

Oxide of aluminum is amphoteric in nature, whereas NaO, MgO and CaO are basic in nature.


Q.4. Which of the following statements is incorrect  ?

A) BFblank subscript 3  is the weakest Lewis acid 

B) Ammonal is a mixture of aluminium compounds and is used in bombs 

C) BFblank subscript 3 exists as dimer 

D) BCIblank subscript 3  does not conduct electricity in its molten state 

Explanation-

 BFblank subscript 3 exists as dimer.


Q.5.  Orthoboric acid contains 

A) Pyramidal B O subscript 3 to the power of 3 minus end exponent  units

B) Linear  B O subscript 3 to the power of 3 minus end exponent units 

C) T-shaped  B O subscript 3 to the power of 3 minus end exponent units 

D) Triangular  B O subscript 3 to the power of 3 minus end exponent units    

Explanation-

Orthoboric acid open parentheses H subscript 3 B O subscript 3 close parentheses contains triangular BO subscript 3 superscript 3 minus end superscript units joined together through H-bonding forming a trigonal planar layer structure.


Q.6. Aluminum deposited as vapors on glass forms a good mirror, essentially because 

A) It has better shine than Ag

B) It does not scratch

C) Coating is  much smoother

D) It does not tarnish in air

Explanation-

Aluminum being passive metal does not tarnish in air.


Q.7. In the electrolytic extraction of aluminum fused cryolite is added

A) To make a conduction solution of bauxite

B) To act as reducing agent

C) To increase Al production

D) To protect the anodes

Explanation-

Addition of cryolite to fused alumina during electrolytic extraction make the solution more conducting and low melting.


Q.8.  Which of the metal chlorides has maximum covalent character ?

A) NaCl

B) AlClblank subscript 3

C) CsCl

D) BaClblank subscript 2 

Explanation-

Al to the power of 3 plus end exponent has minimum size and maximum charges, hence forms compound with maximum covalent character among given choice. The covalent character of chlorides increases along a period and decreases down a group according of Fajan's rule.


Q.9. When concentrated H subscript 2 S O subscript 4 is heated with K N O subscript 3, brown fumes evolve. These fumes are due to

A) S O subscript 2

B) S O subscript 3

C) N O subscript 2

D) N O 

Explanation-

KNO subscript 3 space plus space straight H subscript 2 SO subscript 4 rightwards arrow with triangle on top KHSO subscript 4 space plus space HNO subscript 3
4 HNO subscript 3 space rightwards arrow with triangle on top space 4 NO subscript 2 space plus space 2 straight H subscript 2 straight O space plus space straight O subscript 2
space space space space space space space space space space space space space space space space space space space space space Brown 


Q.10. Which one of the following elements is most metallic ?

A) P

B) As

C) Sb

D) Bi

Explanation-

Metallic character increases down the group.

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